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Understanding LEL vs vol%: A Guide to Gas Concentration Measurements



Introduction

When it comes to measuring gas concentrations, particularly in safety applications, two common units often appear: LEL (Lower Explosive Limit) and vol% (volume percent). Understanding the difference between these measurements is crucial for anyone working with combustible gases or in hazardous environments.



What is LEL?

LEL stands for Lower Explosive Limit, which represents the threshold for how much flammable gas must be present in the air before an explosion or fire can occur. At concentrations below the LEL, the mixture is too "lean" to burn. For example a very small amount of propane in a room will not pose a fire hazard. Nothing will happen if we light a match or create a spark in the room.
If the amount of propane increases, for example as a result of a gas leak, the atmosphere will eventually become ignitable and can explode from a spark. LEL represents precisely the point where the air becomes flammable.

LEL is expressed as a percentage of the minimum concentration required for combustion.
For example, methane has an LEL of 5 vol%. This means that when methane makes up 5% of the total volume of a methane-air mixture, it reaches its lower explosive limit.

image showing relations between LEL and volume percentage
Image showing relations between LEL and volume percentage for Methane (CH4) ISO standard

What is UEL?

All combustible gases have an explosive range - an interval where the atmosphere is flammable. This range starts at LEL - Lower Explosive Limit, and ends with UEL - Upper Explosive Limit. If the air in a room contains 40% propane, the gas mixture is too "thick" to be ignited. We have exceeded the UEL, and the atmosphere is no longer ignitable because there is not enough oxygen present to support a fire. Both LEL and UEL vary from gas to gas. See table on the bottom for most common gases.

We can use two different combustible gases as examples:
Methane (CH4): The lower explosive limit for methane in air is around 5 volume percent. This is the ISO reference. If the atmosphere contains less than 5 volume percent methane, the amount of gas is too small for the air to ignite. When the methane content exceeds 5 volume percent, the fire hazard increases. The UEL for methane is around 15 volume percent. We can therefore say that we have a flammable atmosphere if there is between 5-15 volume percent methane in the air.

Propane (C3H8): The LEL for propane in air is around 2.1 volume percent. The UEL for propane is around 9.5 volume percent. A flammable atmosphere for propane at normal oxygen levels is therefore between 2.1-9.5 volume percent. We can thus see that it takes less propane in a room to exceed the LEL than methane. There is great variation in the explosive range of different gases. The LEL and UEL values should be used as general guidelines as pressure, temperature, and other substances in the air can have an impact on the values.

image showing explosion range for combustible gases
Image showing explosion range for combustible gases

What is vol%?

Volume percent (vol%) is a straightforward measurement indicating the percentage of a specific gas in the total volume of a gas mixture. It's a direct ratio measurement—10 vol% means that 10% of the volume of the gas mixture consists of the target gas.

The Critical Difference

The key difference between LEL and vol% lies in what they reference:


For example, if methane (CH4) has an LEL of 5 vol%, then:


Why Use LEL Instead of vol%?

Safety professionals often prefer LEL because:


Conversion Between LEL and vol%

Converting between LEL and vol% is straightforward when you know a gas's LEL value:

\(\text{Vol%} = (\text{LEL%} \times \text{LEL Value}) \div 100\)

Where "LEL value" is the vol% concentration at which the gas reaches 100% LEL.

For example, with methane (LEL value = 5 vol%):
50% LEL =(50x5) /100 = 2.5 Vol%


Conclusion

While vol% gives you the absolute concentration of a gas, LEL provides crucial context about safety margins. For anyone working with combustible gases, understanding both measurements—and how they relate to each other—is essential for maintaining a safe working environment.


Overview of Explosive Limits for Common Gases (European Standard)

Gas Lower Explosive Limit (LEL) in VOL% Upper Explosive Limit (UEL) in VOL%
Methane 4.4 17.0
Propane 1.7 10.9
Acetylene 2.3 100.0
Carbon Monoxide 10.9 74.0
Heptane 0.85 6.7
Gasoline 1.4 7.6
Hydrogen Sulfide 4.0 45.5
Acetone 2.5 14.3 (100 °C)
Ammonia 15.0 33.6
Benzene 1.2 8.6
Butane 1.4 9.3
Ethylene 2.3 36.0
Toluene 1.0 7.8
Cyclohexane 1.0 8.0
Hexane 1.0 8.9
Hydrogen 4.0 77.0

Overview of Explosive Limits for Common Gases (ISO Standard)

Gas Lower Explosive Limit (LEL) in VOL% Upper Explosive Limit (UEL) in VOL%
Methane 5.0 15.0
Propane 2.1 9.5
Acetylene 2.5 82.0
Carbon Monoxide 12.5 74.0
Hydrogen 4.0 75.0
Ammonia 15.0 28.0
Butane 1.8 8.4
Ethylene 2.7 36.0
Benzene 1.2 7.8
Hexane 1.1 7.5
Acetone 2.5 13.0
Hydrogen Sulfide 4.3 45.0
Ethane 3.0 12.5
Ethanol 3.3 19.0
Methanol 6.0 36.0
Pentane 1.4 8.0